过氧化物和硫固化系统对酸复合材料的物理和机械性能的影响:一项比较研究
Hamed Peidayesh1, Zuzana Nógellová1, Ivan Chodák1
1Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia.
Materials (Basel, Switzerland)
|January 11, 2024
概括
这项研究研究了硫和双过氧化物 (DCP) 化如何影响烯二甲 (NBR) 的特性. 较高的DCP和碳黑 (CB) 含量增加了强度和模量,但减少了延伸,与交叉链密度相关.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 技术 技术 技术
背景情况:
- 乙烯 (NBR) 是一种多用途的合成.
- 火山化对于提高的性能至关重要.
- 对比硫和过氧化物固化系统对于材料优化至关重要.
研究的目的:
- 为了比较硫和二过氧化物 (DCP) 化系统对NBR特性的影响.
- 为了研究碳黑 (CB) 填充剂度的影响.
- 为了将机械性能与交叉链密度和分子移动性相关联.
主要方法:
- 用不同的DCP和CB度制备NBR化合物.
- 使用拉伸试验进行表征,动态机械热分析 (DMTA).
- 确定交叉链密度和溶剂吸收.
主要成果:
- 增加的DCP和CB含量导致更高的抗拉强度和模量.
- 休息时的延长随着DCP和CB的增加而减少.
- 与CB结合的硫固化NBR显示出显著的拉伸强度改善 (13.1到21.2MPa).
- 更高的交叉链密度与增加的存储模量,玻璃过渡温度和刚度相关.
结论:
- DCP和CB显著影响NBR的机械性能,增加强度和刚性.
- 化系统的选择 (硫与DCP) 和填料含量是定制NBR性能的关键因素.
- 观察到的属性变化与交叉链密度和分子流动性的变化一致.
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