通过将金属复合物和可生物降解复合剂集成到超吸收剂中,改善了土壤修饰
Alicja Drozd1, Yongming Ju2,3, Dorota Kołodyńska4
1Analytical Department, Łukasiewicz Research Network-New Chemical Syntheses Institute, Al. Tysiąclecia Państwa Polskiego 13a, 24-110 Puławy, Poland.
Materials (Basel, Switzerland)
|January 11, 2024
概括
超吸收性水凝有效吸附重要的金属离子,如铜,铁,和. 生物降解复合剂显著提高控制释放肥料的吸附效率.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 农业科学 农业科学
背景情况:
- 超吸收性聚合物正在探索用于先进的肥料应用.
- 对必要的微量营养素的控制释放对于现代农业至关重要.
研究的目的:
- 评估Agro®水凝吸附Cu (II),Fe (III),Mn (II) 和Zn (II) 离子的能力.
- 研究新型生物降解复合剂 (IDHA,EDDS,GLDA) 在金属离子吸附中的作用.
- 为了描述吸附过程和水凝材料.
主要方法:
- 批量吸附实验是在静态条件下进行的.
- 分析金属离子度使用诱导合等离子光学发射光谱仪 (ICP-OES).
- 水凝的表征包括FT-IR,ASAP,SEM-EDS和TGA.
主要成果:
- 兰穆尔等温模型最好地描述了吸附平衡.
- 在60分钟内,迅速达到吸附平衡.
- IDHA,EDDS和GLDA的存在提高了金属离子对水凝的吸附效率.
结论:
- 阿格罗®水凝与生物降解复合剂结合,显示出开发可控释放矿物肥的前景.
- 该研究提供了对基本金属离子的吸附机制和效率的宝贵见解.
相关概念视频
Superplasticizers
85
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
85
Waterproofing and Anti-Bacterial Admixtures in Concrete
79
Concrete's susceptibility to water absorption is due to the capillary action within the pores of its hydrated cement paste. This action draws water in, creating the need for waterproofing admixtures to prevent such penetration. The efficacy of these admixtures is contingent upon the water pressure, with variations arising from different conditions such as rain, capillary rise, or hydrostatic pressure in structures intended to hold water.
Waterproofing admixtures render concrete hydrophobic,...
Waterproofing admixtures render concrete hydrophobic,...
79
Extraction: Advanced Methods
447
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
447
Coagulation
299
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
299
Bioremediation
18.4K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.4K
Complexation Equilibria: The Chelate Effect
518
In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
518


