具有低和高温度的3D打印液晶聚合物的机械性能
Kai S Johann1, Andreas Wolf1, Christian Bonten1
1Institut für Kunststofftechnik, University of Stuttgart, 70569 Stuttgart, Germany.
Materials (Basel, Switzerland)
|January 11, 2024
概括
本研究探讨在化丝制造 (FFF) 中使用液晶聚合物 (LCP). 较低化温度的LCP更适合FFF,通过优化打印参数产生更好的机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 增材制造 增材制造 增材制造
背景情况:
- 增材制造 (AM) 可以在没有模具的情况下创建复杂的零件,使用塑料,金属和陶.
- 像PEEK和PEI这样的高性能聚合物是在AM中建立的.
- 热热型液晶聚合物 (LCPs) 在液态阶段表现出独特的异热性特性,与传统聚合物不同.
研究的目的:
- 研究热otropic液晶聚合物 (LCPs) 适用于化丝制造 (FFF) 的适用性.
- 将LCPs的可加工性和机械性能与低 (约. 280°C) 和高 (大约. 330°C) 的融化温度在FFF中.
主要方法:
- 两种不同化温度的LCP的化丝制造 (FFF).
- 过程参数的系统变化:沉积方向,打印温度,打印速度和层高度.
- 印刷LCP组件的机械性能测试 (斯模量,抗拉强度).
- 印刷后回火处理,以评估其对机械性能的影响.
主要成果:
- 在0.10毫米的层高度下,达到27.3 GPa的扬斯模量.
- 在0.15毫米的层高度下,通过印刷后回火增加了高达406MPa的抗拉强度.
- 证明机械性能高度依赖于工艺参数和LCP化温度.
结论:
- 液晶聚合物 (LCP) 显示为化丝制造 (FFF) 的前景.
- 具有较低融温度的LCP对于FFF加工和实现优异的单轴机械性能更有利.
- 优化工艺参数和后处理步骤,如化,对于最大限度地提高AM中的LCP性能至关重要.
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