从天然气中吸附硫化,使用修改为银的13X分子
Mirzokhid Abdirakhimov1, Mohsen H Al-Rashed2, Janusz Wójcik1
1Department of Chemical Engineering and Process Design, Silesian University of Technology, 44-100 Gliwice, Poland.
Materials (Basel, Switzerland)
|January 11, 2024
概括
修改为银的13X分子有效地从天然气中去除有毒的硫化 (H2S). 与未经修改的版本相比,这种增强的热带石的吸附能力增加了50倍.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 硫化 (H2S) 是天然气,沼气和炼油厂气体中存在的有毒和腐蚀性气体.
- 有效的H2S去除对于气体处理,安全和环境保护至关重要.
- 由于它们的多孔结构,石通常用于H2S吸附.
研究的目的:
- 为了增强13X分子的H2S吸附特性.
- 研究银 (Ag) 交换和AgNO3度对吸附能力的影响.
- 为了评估银改性13X在天然气中去除H2S的性能.
主要方法:
- 使用不同度的AgNO3制备Ag交换的13X分子.
- 使用XRD,SEM和BET技术对合成材料进行表征.
- 使用实验室固定床吸附器设置对吸附性质的评估.
主要成果:
- 吸附能力随着AgNO3度增加到0.05M,增加了.
- 度为0.1M的AgNO3导致更快的突破时间,表明容量减少.
- 与未经修改的13X相比,AgII-13X的吸附能力增加了50倍.
结论:
- 修改为银的13X分子具有显著增强的H2S吸附能力.
- 优化的白银交换是最大化H2S去除效率的关键.
- 这种材料显示出从天然气中提取H2S的工业应用的巨大潜力.
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