用甲对软木和硬木的 kraft 体进行甲基化
Daniel Beaudoin1, Ernest Palus1, Mohan K R Konduri2
1FPInnovations - Bioproducts Innovation Centre of Excellence 570 Saint-Jean Boulevard, Pointe-Claire Québec H9R 3J9 Canada daniel.beaudoin@fpinnovations.ca.
RSC advances
|January 12, 2024
概括
使用甲甲基的 kraft 素的甲基化提供了一种具有成本效益和环保的方法. 这一过程改善了红素的特性,如热稳定性和聚合物与良性副产品的兼容性.
科学领域:
- 生物质价值化 生物质价值化
- 绿色化学是一种绿色化学.
- 聚合物科学 聚合物科学
背景情况:
- 氨酸甲基化增强了热稳定性,聚合物混合的兼容性,并降低了玻璃过渡温度.
- 传统的甲基化方法通常使用昂贵,有毒的试剂,原子经济性差.
研究的目的:
- 开发一种高效,环保的甲基化工艺,用于软木和硬木的 kraft 烯酸.
- 在性水性介质中利用甲作为甲基化剂.
主要方法:
- 使用甲进行实力金甲基化.
- 反应在90-110°C和40 psi的性水性介质中进行.
- 对反应产量和副产品的分析.
主要成果:
- 实现了甲基化红素的高产量.
- 生产的对环境无害的副产品 (化和水).
- 成功地甲基化了软木和硬木的 kraft 质.
结论:
- 在性水性介质中甲甲基化是一种可行的,高产率的工艺,用于素修饰.
- 这种方法为传统的素甲基化技术提供了更绿色的替代方案.
- 修改后的素对潜在的聚合物应用具有更好的性能.
相关概念视频
Radical Substitution: Halogenation of Alkanes and Alkyl Substituents
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In the presence of heat or light, alkanes react with molecular halogens to form alkyl halides by a substitution reaction called radical halogenation. This reaction has three steps: initiation, propagation, and termination, as seen in the radical chlorination of methane to produce methyl chloride.
In the initiation step of the reaction, the chlorine molecule undergoes homolytic cleavage in the presence of light or heat, forming two highly reactive chlorine radicals. Propagation occurs in two...
In the initiation step of the reaction, the chlorine molecule undergoes homolytic cleavage in the presence of light or heat, forming two highly reactive chlorine radicals. Propagation occurs in two...
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A method involving the transformation of methyl ketones to carboxylic acids using excess base and halogen is called the haloform reaction. It begins with the deprotonation of α hydrogen to form an enolate ion which reacts with the electrophilic halogen to give an α-halo ketone. The step continues until all the α protons are substituted to form a trihalomethyl ketone. The resulting molecule is unstable, and in the presence of a hydroxide base, it readily undergoes nucleophilic...
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Carboxylic acids react with diazomethane in an ether solvent via alkylation at the carboxylate oxygen atom to give methyl esters of the corresponding acid with excellent yields.
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