具有不同维度的双聚合Y受体可以创建像神经元一样的相互透的层次网络,以实现高效和稳定的全聚合物太阳能电池
Jingjing Ji1, Zhiyuan Wu1, Jiaqi Xie1
1Department of Materials Science, Fudan University, Shanghai, 200433, China.
Advanced materials (Deerfield Beach, Fla.)
|January 12, 2024
概括
研究人员开发了一种全聚合物太阳能电池的新型Y分支聚合物接受器 (PYBF). 将PYBF与少量线性PYIT混合改善了形态,并实现了17%的冠军功率转换效率 (PCE).
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 全聚合物太阳能电池为制造提供了出色的稳定性.
- 大量异质连接活性层的形态挑战限制了性能.
- 需要新的接受器材料来克服这些限制.
研究的目的:
- 设计和合成一个3DY分支的聚合小分子接受器 (PYBF).
- 研究PYBF独特结构对太阳能电池形态和性能的影响.
- 为了提高全聚合物太阳能电池的功率转换效率 (PCE) 和稳定性.
主要方法:
- 通过与Y6受体结合佐特里uran,合成PYBF受体.
- 使用PYBF和聚合物供体PM6.的批量异质连接太阳能电池的制造.
- 用不同的接受器混合物进行太阳能电池的形态分析和性能测试.
主要成果:
- PYBF具有高分子量和玻璃过渡温度.
- 与线性PYIT相比,基于PYBF的细胞实现了15.7%的PCE,与线性PYIT相比,结晶性和方向得到了改善.
- 将少量的PYIT与PYBF结合起来解决了相隔问题,形成了类似神经元的双接受器域,并实现了约17%的冠军PCE.
结论:
- 类似恒星的PYBF结构最初导致了不利的相位分离.
- 双受体系统 (PYBF/PYIT) 显著改善了形态,减少了重组,并促进了PCE.
- 优化的全聚合物太阳能电池表现出卓越的热和存储稳定性.
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