全面的层次结构,优化的载体度和带操纵导致环保MnTe的超高热电性能
Shahzada Zulkifal1, Suniya Siddique1, Zhichao Wang2
1National Key Laboratory of Advanced Casting Technologies, MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology, Engineering Research Center of Materials Behavior and Design, Ministry of Education, Nanjing University of Science and Technology, Nanjing, 210094, China.
Small (Weinheim an der Bergstrasse, Germany)
|January 12, 2024
概括
这项研究增强了化 (MnTe) 的中温热电应用. 与和银合金优化电子性能并创建分层结构,实现1.5.5的ZT记录.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 热电学是一种热电学.
背景情况:
- 化 (MnTe) 由于其环保和丰富的性质,对中温热电器具有前景.
- 现有的MnTe材料需要优化以提高其热电性能 (ZT).
研究的目的:
- 为了提高MnTe的热电特性,用于中温应用.
- 通过带结构工程和微观结构修改来实现高功率 (ZT).
主要方法:
- 加入 (Pb) 和银 (Ag) 来实现价值带的融合,并优化载体度.
- 与Pb合金,将PbTe纳米棒引入到MnTe矩阵中,创建分层的微观结构.
- 显微结构演变的表征和热电性质测量.
主要成果:
- 通过Pb和Ag的配合,实现了多重价值带的融合和增强载体度,从而提高了功率因子.
- 设计了各种规模的层次架构,包括PbTe纳米棒,点缺陷散射,位移和堆叠故障.
- 将网格导热率降低到0.376 W m-1 K-1.1,创纪录的低点.
- 获得了1.5.5的超高热电功率 (ZT).
结论:
- 价值带趋同,优化载体度和全尺度层次结构的结合显著提高了MnTe的热电性能.
- 实现的ZT1.5超过了之前报告的大多数基于MnTe的热电材料,突出了其实际应用的潜力.
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