通过预分解导电探测介电聚合物的电子带结构
Zongze Li1,2, Chao Wu1,2,3, Lihua Chen4
1Electrical Insulation Research Center, University of Connecticut, 97 N Eagleville Rd, Storrs, CT, 06269, USA.
Advanced materials (Deerfield Beach, Fla.)
|January 12, 2024
概括
了解介电材料中的电子带结构是防止电气降解的关键. 这项研究探测了聚合物薄膜的分解前导电性,揭示了影响电性能的缺陷状态.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 电气工程 电气工程
背景情况:
- 电子带结构,特别是缺陷状态,在高电场下的介电材料中控制电子传输和电降解.
- 在分解前条件下对介电带结构的实验研究具有挑战性.
研究的目的:
- 在预分解条件下探测聚合物介电薄膜的电子带结构.
- 为了将材料形态与电子性质和电导行为相关联.
主要方法:
- 在现场预分解导电测量.
- 空间电荷有限电流光谱分析.
- 密度函数理论 (DFT) 对状态密度的计算.
主要成果:
- 观察到导电带尾部缺陷状态的指数分布,并具有不同的陷水平.
- 与聚合物介电的形态障碍相关的缺陷状态.
- 实验缺陷状态和DFT计算的状态密度之间的证明一致.
结论:
- 开发的方法将分子结构与电子带结构和宏观电导联系起来.
- 提供了对控制电气分解的材料特性更深入的了解.
- 为修改现有材料和探索用于高电场应用的新型介电材料提供了一条途径.
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