从性废水中有效地去除和转化Cr(VI) 以通过修改后的铁酸盐工艺形成铁旋多相
Yingying Lan1, Yiwei Sun1, Shasha Chu1
1School of Environment and Energy, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou, Guangdong, 510006, PR China.
Chemosphere
|January 12, 2024
概括
一种新铁素工艺有效地从废水中去除有毒的六价 (Cr(VI),将其转化为有价值的铁素复合材料. 这种方法显著提高了重金属清除效率,并符合环境排放标准.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 废水中的六价 (Cr(VI)) 构成重大环境风险.
- 传统的铁矿工艺在温和条件下难以完全处理Cr.
- 从废水中回收金属是经济和环境的理想选择.
研究的目的:
- 开发一种改进的铁矿工艺,以有效地去除Cr (VI) 和回收.
- 为了研究结合FeSO4降解和铁酸盐复合物形成的水热处理.
- 评估新工艺的效率和环保合规性.
主要方法:
- 结合硫酸铁 (FeSO4) 降解与水热处理以沉.
- 分析Cr(VI) 度的降低和产生的沉物的浸出毒性.
- 描述沉物的组成和结构,确定它是微米大小的铁旋多相.
主要成果:
- 在最佳条件下将Cr (VI) 度从1040毫克L-1降至0.035毫克L-1 .
- 在沉中达到0.21毫克L-1的Cr (VI) 漏毒性.
- 形成的沉物是一个微米大小的铁旋多相,具有多面体结构.
结论:
- 这种新铁工艺有效地去除了Cr (VI) 并将作为铁复合材料回收.
- 该工艺符合工业废水排放和危险废物标准.
- 与传统的铁矿工艺相比,这种方法可以提高有毒重金属的去除效率.
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