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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

63.2K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
63.2K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

23.9K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
23.9K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.1K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.1K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.3K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.3K
Interfacial Electrochemical Methods: Overview01:06

Interfacial Electrochemical Methods: Overview

250
Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current...
250

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相关实验视频

Updated: Jul 5, 2025

High Temperature Fabrication of Nanostructured Yttria-Stabilized-Zirconia YSZ Scaffolds by In Situ Carbon Templating Xerogels
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对于石榴石电解质的固体接口

Wuliang Feng1,2, Yufeng Zhao2, Yongyao Xia1

  • 1Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200433, China.

Advanced materials (Deerfield Beach, Fla.)
|January 12, 2024
PubMed
概括
此摘要是机器生成的。

石榴石固态电解质 (SSEs) 为固态电池 (SSLB) 提供高性能. 这项研究解决了诸如状物生长和接触问题等界面挑战,并提出了稳定策略,以提高电池的安全性和效率.

关键词:
石榴石的石榴石是指一个石榴石的石榴石.接口 接口 接口 接口 接口二二二二二二二二固态系统的固态状态.稳定的稳定性 稳定的稳定性

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 固态电解质 (SSEs) 对于高能量密度和安全的二次电池至关重要.
  • 石榴石类型的SSE显示出对固态电池 (SSLB) 的承诺,因为其高离子导电性和低还原潜力.
  • 挑战包括面接接触差以及石榴石弹性模量和电子导电引起的树增长.

研究的目的:

  • 审查最近在SSLB中石榴石电解质的固体接口方面的进展.
  • 提出抑制树生长和稳定接口的策略.
  • 为基于石榴石的SSLB的实际应用和未来发展提供见解.

主要方法:

  • 关于石榴石基固态电解质的最新文献的综述.
  • 对界面稳定策略的分析,包括化学,电化学和机械方法.
  • 讨论树抑制技术和相间设计.

主要成果:

  • 石榴石SSEs面临着影响SSLB性能和安全的界面挑战.
  • 已经开发出有效的界面稳定和树抑制策略.
  • 介绍了一种关于界面性胆固醇恐惧症的新视角.

结论:

  • 优化固体接口是释放基于石榴石的SSLB的全部潜力的关键.
  • 这项工作为SSEs的界面稳定提供了全面的理解.
  • 石榴电解质的进步对于SSLB行业的未来至关重要.