化学结构特征和煤炭的模型构造,具有三种类型的凝聚度
Chengyong Wang1,2, Yaowen Xing2, Kaiyi Shi3
1School of Mining and Mechanical Engineering, Liupanshui Normal University, Liupanshui 553004, Guizhou, China.
ACS omega
|January 15, 2024
概括
这项研究使用光谱学开发了精确的煤结构模型. 这些模型揭示了煤炭结构如何随着聚合变化而变化,影响了像可湿性这样的特性.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 频谱学是一种光谱学.
背景情况:
- 了解煤炭结构对于煤炭性质研究至关重要.
- 需要精确的煤炭结构模型来推进这些研究.
研究的目的:
- 开发一种半定量方法,用于构建煤炭结构模型.
- 分析煤炭结构的演变与增加的聚合程度.
- 为了验证开发的模型,并解释煤炭湿度差异.
主要方法:
- 福里埃变换红外光谱法 (FTIR) 光谱法
- 在X射线衍射 (XRD) 中.
- 在X射线光电子光谱学 (XPS) 中.
主要成果:
- 煤的芳香核心大小随着聚合而增加.
- 阿里法性结构增加,含氧功能群 (OFG) 减少,从煤到煤.
- 阿里法性结构减少,OFG略有增加,从煤到炭酸盐.
- 模型计算的FTIR光谱与实验数据相匹配,证实了模型的准确性.
结论:
- 拟议的半定量方法准确地模拟了煤炭结构.
- 这些模型解释了煤炭湿度变化的微观机制.
- 开发的方法和模型在未来的煤炭研究中具有广泛的应用性.
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