可逆多模式发光调制在光染色半透明Yb3+/Eu3+编K0.5Na0.5NbO3陶中
Hui Huang1, Lingjie Wu1, Ting Zheng1
1College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China.
Inorganic chemistry
|January 15, 2024
概括
这项研究合成了可调节的发光酸尼奥酸盐 (KNN) 铁电陶,用欧 (Eu) 和 (Yb) 添加剂. Yb含量有效地控制了上转换和下转换的发光,从而实现了可逆光色.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 发光的光度是非常的低.
背景情况:
- 可调节的发光材料对于光学应用,如开关和数据存储至关重要.
- 欧 (Eu) 是一个已知的红色下转换发射器,但其在酸盐酸盐 (KNN) 铁电中的上转换发光和光色是未被充分探索的.
研究的目的:
- 合成和研究Eu3+和Yb3+联合合的KNN半透明铁电陶.
- 探索Yb3+度对这些陶的发光和光色特性的影响.
主要方法:
- 合成Eu3+和Yb3+联合合的KNN半透明铁电陶.
- 上向转换和下向转换的发光特性.
- 通过405nm光照明诱导的光染色的研究.
- 分析氧空位演变,晶体场变化和电子偏磁共振 (EPR) 信号.
主要成果:
- Yb3+含量精确控制了上转换和下转换的发光强度和衰变速率.
- 实现了可逆的,光色向上转换的发光陶,在405nm光照的10秒内变色.
- 发光调制与氧气空位动态,晶体场变化,EPR信号和压响应切换相关.
结论:
- 该研究展示了一种在铁电陶中设计高性能,可逆,多模式发光调节的方法.
- 这些发现为开发具有可调节发光和光色功能的先进光学材料提供了新的范式.
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