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纳米级的酸融化质地决定了火山灰表面的化学成分
Adrian J Hornby1,2, Paul M Ayris3, David E Damby4
1Department of Earth and Atmospheric Sciences, Cornell University, Ithaca, NY, USA. ahornby@cornell.edu.
Nature communications
|January 15, 2024
概括
火山灰表面因碎片化过程而与其散装成分有很大差异. 了解这些初始表面变化对于预测灰对环境的影响至关重要.
科学领域:
- 地质化学 地质化学
- 火山学 火山学是一门学科.
- 材料科学 材料科学 材料科学
背景情况:
- 爆炸性火山喷发会产生酸盐灰,其表面在大气中转移时会发生变化.
- 改变的灰表面会影响环境相互作用,如冰核和生物毒性等.
- 之前的研究假设由于未知的初始状态,灰表面化学与散装成分相匹配.
研究的目的:
- 为了研究由受控火山碎片化产生的灰颗粒的初始表面化学.
- 为了确定碎片化是否会产生与散装成分相比不同的表面化学成分的灰颗粒.
主要方法:
- 安德西特火山材料的受控碎片化.
- 对产生的灰颗粒表面化学的分析.
主要成果:
- 碎片化产生灰颗粒,表面化学有显著差异.
- 纳米级化的异质性,特别是富含铁的纳米相,会影响碎片化过程中的断裂传播.
- 爆发前的微组织可以改变断裂路径,导致灰表面化学的初级差异.
结论:
- 火山灰表面的化学成分并不等同于碎片化后立即出现的散装成分.
- 化的异质性和爆发前的微观结构是控制初始灰表面化学的关键因素.
- 这些发现对于了解活性火山灰对环境的影响至关重要.
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