聚乙烯纳米纤维的环境催化线
Ruikai Wu1,2, Tim M Lenz3, Fayez Abdullah S Alfayez1
1Laboratory of Advanced Fibers, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstrasse 5, 9014, St. Gallen, Switzerland.
Angewandte Chemie (International ed. in English)
|January 16, 2024
概括
这项研究引入了一种新型的单原子催化剂,该催化剂在纳米通道中固定,用于乙烯聚合,产生高度均的聚乙烯纳米纤维. 这种方法可以使连续的,轻度的催化 (CATSPIN) 直接变成纤维形式,并最小的分支.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 催化剂是一种催化剂.
背景情况:
- 封闭空间聚合提供了对聚合物架构的独特控制.
- 开发用于直接聚合物纤维合成的高效催化剂是一个关键的挑战.
- 单原子催化剂提供高活性和选择性.
研究的目的:
- 开发一种新的单原子催化剂,用于局限空间的乙烯聚合.
- 通过催化线研究聚乙烯 (PE) 纳米纤维的直接合成.
- 探索纳米封闭对PE特性和聚合行为的影响.
主要方法:
- 一个单原子Ni (II) 催化剂的共价固定在半孔SBA-15和AAO纳米通道上.
- 使用ICP-OES和XPS进行表征,以确认催化剂的存在.
- 在环境温度下的纳米反应器内以乙烯挤出聚合.
主要成果:
- 均的PE纳米纤维 (直径约50纳米) 被生产出来,具有高度定向的形态.
- 合成的PE具有高分子量 (1.62×10^6 g/mol),高点 (124°C) 和高晶度 (41.8%).
- 纳米封闭显著减少了链条的分支 (13.6/1000 C) 和纠.
结论:
- 开发的Ni-催化封闭空间聚合使低分支PE纳米纤维的直接合成成为可能.
- 这种方法为连续轻度催化 (CATSPIN) 工艺铺平了道路.
- 该方法克服了聚合物纤维生产中热降解和分子纠的局限性.
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