在电子喷雾羽毛中蒸汽形成的高速施莱伦成像
Hou-I Li1, Gurpur Rakesh D Prabhu1, Krzysztof Buchowiecki1
1Department of Chemistry, National Tsing Hua University, 101, Section 2, Kuang-Fu Rd., Hsinchu 300044, Taiwan.
Journal of the American Society for Mass Spectrometry
|January 16, 2024
概括
在电子喷雾中可视化了蒸汽的形成,揭示了流和层流的流动模式. 滴滴惯性,而不是电场,驱动蒸汽速度,为现代电喷离子化 (ESI) 系统提供了洞察力.
科学领域:
- 分析化学 分析化学
- 物理化学 物理化学
- 化学物理 化学物理
背景情况:
- 电子喷雾机理学研究传统上侧重于滴滴动力学.
- 在电子喷雾羽毛中产生蒸汽和溶解仍然不太被探索.
- 了解蒸汽行为对于优化电子喷雾电离 (ESI) 性能至关重要.
研究的目的:
- 为了研究蒸汽的产生和传播在一个电喷雾羽毛.
- 分析影响蒸汽流速和流程模式的因素.
- 提供适用于现代电子喷雾电离 (ESI) 装置的见解.
主要方法:
- 实现一个双通轴上的schlieren高速成像系统.
- 在不同的电子喷雾条件下 (电压,流速,溶剂度) 观察蒸汽动态.
- 使用公司内部开发的图像处理来对蒸汽流量进行定量分析.
主要成果:
- 观察到流和层流蒸汽流之间的切换,归因于发射器干扰.
- 证明了平均蒸汽速度对电喷压的微弱依赖,表明中性蒸汽.
- 确定滴滴惯性是蒸汽速度的主要来源,分析物质质量影响最小.
结论:
- 电子喷雾中的蒸汽速度主要由滴滴惯性控制,而不是电场.
- 关于蒸汽流动力学的发现对于优化现代电喷离子化 (ESI) 源具有重要意义.
- 这项研究提供了对电喷雾羽毛中的蒸汽行为的基本理解.
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