基于飞的含水泥材料的长期稳定性风险评估:动态和半动态漏
Mingliang Zhang1, Ying Wu1, Yinmei Li1
1College of Agriculture and Biological Science, Dali University, Dali, 671003, Yunnan, China; Key Laboratory of Ecological Microbial Remediation Technology of Yunnan Higher Education Institutes, Dali, 671003, Yunnan, China.
Environmental pollution (Barking, Essex : 1987)
|January 16, 2024
概括
这项研究评估了基于飞灰的水泥材料在酸雨下的长期稳定性. 结果显示,地质聚合物有效地稳定重金属,减少废物再利用的环境风险.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 地质化学 地质化学
背景情况:
- 城市固体废物焚烧飞灰 (MSWIFA) 由于可浸的重金属 (HMs) 构成环境风险.
- 在酸雨等环境压力因素下评估MSWIFA材料的长期稳定性对于安全处置和资源利用至关重要.
研究的目的:
- 在模拟酸雨条件下,研究含 (FCAC) 的飞基水泥材料的长期稳定性和浸出行为.
- 通过使用顺序提取程序和潜在风险评估指数,评估FCAC中重金属的环境风险.
主要方法:
- 动态和半动态漏测试在模拟酸雨下对FCAC进行了不同颗粒大小的动态和半动态漏测试.
- 使用顺序提取程序 (SEP) 来确定重金属的化学物种化和流动性.
- 使用潜在风险评估指数来量化与FCAC相关的环境风险.
主要成果:
- 观察到溶解和随后的合物形成,以及硫化物氧化产生的酸生成,导致液pH值降低.
- 出水表现出三个不同的阶段 (初始,快速,缓慢),受颗粒大小的影响,最大度为2.42 mg/L.
- 据SEP分析显示,重金属状态转向不太流动的形式,从而降低了整体风险.
结论:
- MSWIFA的地质聚合是一种稳定危险废物的有希望的方法.
- 通过这一过程将MSWIFA重新转化为建筑材料,为废物管理和资源回收提供了一个可持续的解决方案.
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