立体复合PLA用于炼线的特性
Boris Marx1, Lars Bostan1, Axel S Herrmann1,2
1Faserinstitut Bremen, Am Biologischen Garten 2-Geb. IW3, D-28359 Bremen, Germany.
Polymers
|January 17, 2024
概括
高强度生物聚合物纤维提供可持续的解决方案. 立体复合聚乳酸 (scPLA) 呈现出增强的结晶性和热稳定性,为先进的技术织应用铺平了道路.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 织工程 织工程 织工程
背景情况:
- 生物聚合物纤维是环保的替代品,但通常缺乏足够的强度用于织应用.
- 开发高性能生物聚合物纤维对于可持续的资源和环境保护至关重要.
研究的目的:
- 从高分子量聚乳酸 (PDLA) 和聚乳酸 (PLLA) 中呈现立体复杂聚乳酸 (scPLA) 的技术规模形成.
- 为了比较scPLA的性能和融行为与用于纤维生产的标准半晶体PLA (msPLA).
主要方法:
- 差分扫描热度计 (DSC) 用于确定结晶度.
- 用X射线衍射 (XRD) 分析晶体结构.
- 淋病学分析 (造) 和热重力测量分析 (TGA) 来评估加工和稳定性.
主要成果:
- 与msPLA (47.0%) 相比,scPLA实现了更高的结晶度 (59.7%).
- XRD证实了scPLA的纯立体复杂晶体结构和msPLA的半晶体性.
- scPLA的复合粘度低于msPLA,但具有类似的粘弹性行为;热稳定性和生物降解性分别受到分子量和结晶性的影响.
结论:
- scPLA显示出卓越的结晶性和造纤维具有技术强度的潜力.
- 这些发现支持scPLA作为一种有前途的材料,用于开发具有更好的性能特征的先进技术织品.
- 结晶性是影响PLA材料生物降解性的关键因素.
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