水热氨碳化草的水合炭水化物从水溶液中分离Cd (II) 和Zn (II) 离子
Jiarui Wang1,2, Xiaocheng Wei1,2, Hao Kong1,2
1Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, No. 31 Fukang Road, Nankai District, Tianjin 300191, China.
Polymers
|January 17, 2024
概括
研究人员使用大米和所污水,制造出N/P兴奋剂的水电. 这种增强的碳化合物显著提高了产量,并改善了水中的和金属离子的吸附.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 水炭是一种有前途的吸附剂,可以从水溶液中去除金属离子.
- 原料大米的低碳化合物产量限制了其实际应用.
- 水热碳化 (HTC) 涉及脱水,聚合和碳化.
研究的目的:
- 为了提高米草的碳化合物产量,使用修改后的HTC.
- 为了研究N/P兴奋剂合的米水化合物的吸附性能,以去除重金属.
- 了解Cd2+和Zn2+在改性水化合物上的吸附机制.
主要方法:
- 用所污水作为溶剂和N/P源进行了水热碳化.
- 使用X射线衍射 (XRD),X射线光电子光谱 (XPS),扫描电子显微镜 (SEM) 和福利埃转换红外光谱 (FTIR) 进行修改后的化物的表征.
- 在Cd2+和Zn2+的单金属和双金属系统中进行了吸附实验.
主要成果:
- 与传统的HTC相比,所污水的碳化合物产量显著增加.
- 与N/P相配合的米水炭对Cd2+和Zn2+的吸附能力比未经修改的水炭高1.1至1.4倍.
- 兰迈尔和伪二阶模型准确地描述了金属吸附动力学和异热量.
- 吸附机制包括表面复杂化,静电相互作用,键和离子交换.
结论:
- 使用所污水生产的N/P兴奋剂合米水炭是一种有效和高产的Cd2+和Zn2+吸附剂.
- 修改后的炭为废水处理和资源回收提供了一种可持续的方法.
- 表面复杂化,静电相互作用,结合和离子交换是金属离子去除的关键机制.
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