使用疏水性深层欧性溶剂形成以乙醇胺为媒介的无表面活性剂的微乳液
1Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi110016, India.
Langmuir : the ACS journal of surfaces and colloids
|January 17, 2024
概括
疏水性深层浸泡溶剂 (HDES) 可以与水形成无表面活性剂的微乳液 (SFME),使用乙醇胺 (ETA) 作为水管. 这些新型系统显示出溶解酸铁酸盐等盐的潜力.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 疏水性深度浸泡溶剂 (HDES) 为传统有机溶剂提供了可持续的替代品.
- 使用HDES作为油相的微乳液形成是一个新兴的研究领域.
- 由于表面活性剂的毒性问题,无表面活性剂微乳液 (SFME) 的需求日益增加.
研究的目的:
- 为了研究SFME的形成,使用HDES作为油阶段和水作为水友性阶段.
- 探索乙醇胺 (ETA) 的水热潜力,以促进SFME与HDESs的形成.
- 描述由此产生的微观结构及其溶解盐的能力.
主要方法:
- 使用n-decanoic acid和五种不同的 terpenoids,制定了HDES.
- 乙醇胺 (ETA) 被用作水物来增强HDESs中的水溶性.
- 构建了三相图,并使用动态光散射 (DLS) 来研究纳米聚合物形成.
- 光谱学和酒-兰伯特定律被用来探测微观结构和盐溶性.
主要成果:
- 乙醇胺显著增加了HDES中的水溶性,作为一种有效的水.
- 为每个HDES系统确定了最佳水热度 (X_ETA^OPT) 和水负载.
- 动态光散射揭示了纳米聚合物的系统增长和水添加后的微观结构变化.
- 在"奥佐前"地区推断出一个类似核心外 (油水) 的结构.
- 在SFME中制备了酸铁化物的均溶液,而不会偏离Beer-Lambert法.
结论:
- 无表面活性剂的微乳液可以成功地使用HDES和乙醇胺作为水基形成.
- 开发的系统具有可调节的微观结构,可以溶解无机盐,这表明了潜在的应用.
- 这些发现有助于开发用于各种化学过程的更绿色的溶剂系统.
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