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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.3K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.3K
Structures of Solids02:22

Structures of Solids

14.1K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
14.1K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.6K
Metallic Solids02:37

Metallic Solids

18.4K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.4K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

26.5K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.5K

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相关实验视频

Updated: Jul 5, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

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模拟结构和离子扩散在一个类的离子液晶基固体电解质的离子结构和离子扩散.

Md Sharif Khan1, Ambroise Van Roekeghem1, Stefano Mossa2

  • 1Université Grenoble Alpes, CEA, LITEN, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France. sharifkhanjnu@gmail.com.

Physical chemistry chemical physics : PCCP
|January 18, 2024
PubMed
概括
此摘要是机器生成的。

我们开发了新的液晶电解质,用于更安全,高效的离子电池. 离子导电性取决于纳米通道的大小和离子相互作用,显示了固态电池设计的前景.

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

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相关实验视频

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 化学工程是化学工程的重要组成部分.

背景情况:

  • 下一代离子电池需要安全且热稳定的电解质.
  • 液晶为先进的电池应用提供了固体和液体之间的有希望的中间阶段.

研究的目的:

  • 设计和分析一种新的液晶电解质,用于高性能,全固态离子电池.
  • 研究基链长度对离子导电性和自我组织的影响.

主要方法:

  • 用分子动力学模拟来分析电解质结构和特性.
  • 用于合成和表征液晶电解质的各种实验技术.
  • 用不同的链长度来评估离子导电性.

主要成果:

  • 新型,高度排序的叶片相液晶电解质以99%的纯度进行了合成.
  • 发现离子导电性不单调地取决于基链长度,与纳米通道形成相关.
  • 离子对相互作用显著影响整体导电性.

结论:

  • 开发的液晶电解质显示了固态离子电池的潜力.
  • 优化基链长度和了解离子对相互作用是提高离子导电性的关键.
  • 这种新的电解质类别为更安全,高效的储能提供了有前途的途径.