压力循环诱导的MnBi2Te4的过渡行为
Jie Wu1,2, Yan Feng3, Yifeng Ren2
1Center for High Pressure Science and Technology Advanced Research, Shanghai 201203, China.
The Journal of chemical physics
|January 18, 2024
概括
对MnBi2Te4的高压研究揭示了15GPa以下不可逆转的金属-半导体-金属转换. 在17GPa以上,压缩会损坏结构,导致压缩后具有纳米粒的无形状态.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 量子材料是一种量子材料.
背景情况:
- MnBi2Te4是一种已知的材料,可以容纳异国情调的拓量子态.
- 这些状态与其独特的晶体结构密切相关.
- 了解其在极端条件下的行为对于探索新的量子现象至关重要.
研究的目的:
- 为了研究MnBi2Te4在多个高压周期下的相位过渡行为.
- 在MnBi2Te4.4中确定结构和电子相位过渡的压力值.
- 探索在高压下诱导或保存拓相的潜力.
主要方法:
- 使用钻石芯用于高压生成和研究.
- 在MnBi2Te4样本上进行多次压力循环实验.
- 分析不同压力水平引起的结构和电子变化.
主要成果:
- 在不超过15GPa的压力下,观察到一种不可逆转的金属-半导体-金属过渡.
- 在17GPa以上的压力下,由于晶格扭曲,层层结构发生了不可逆转的无形化.
- 在解压后,材料保留了一些纳米大小的颗粒,表明不完全无形化.
结论:
- 在循环高压下,MnBi2Te4表现出明显的相位过渡路径.
- 层层结构的完整性在17GPa以上受到损害,导致了重大结构变化.
- 这项研究为操纵MnBi2Te4在压力下的特性提供了实验性见解,可能有助于发现高压拓相.
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