基于Zwitterionic化的pyrazolo-triazole的高性能能量材料
Parasar Kumar1, Navaneet Kumar1, Vikas D Ghule2
1Energetic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, Uttar Pradesh, India. srinivasd@iitk.ac.in.
Chemical communications (Cambridge, England)
|January 18, 2024
概括
合成了新的富含的化能量材料. 化合物3和4显示出高爆炸速度和出色的安全性质,为下一代热稳定的能量材料提供了潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 能量材料对于各种应用至关重要.
- 开发具有增强性能和安全性的新能源材料是一个正在进行的研究领域.
- 富含的化合物由于其高热度的形成和燃烧产品而引起了特别的兴趣.
研究的目的:
- 为了合成和描述一系列新的富含的化能量材料.
- 为了评估合成化合物的引爆性能,灵敏度和热稳定性.
- 探索这些材料作为下一代能量化合物的潜力.
主要方法:
- 从廉价的原材料合成富含的化能量材料.
- 使用1H和13C的NMR,IR光谱和元素分析进行了完整的表征.
- 通过单晶X射线衍射 (SCXRD) 阐明zwitterionic化合物2的结构.
- 使用差分扫描热量计 (DSC) 的热量分析.
- 评估爆炸速度,摩擦灵敏度和冲击灵敏度.
主要成果:
- 成功合成了几种富含的化能量材料.
- 化合物3和4表现出极好的爆炸速度 (8956和9163米/秒).
- 这些化合物表现出对摩擦 (>360 N) 和冲击 (10 J) 的高不敏感性.
- 对化合物3和4 (171-262 °C) 观察到中等到优良的热稳定性.
- 兹维特里昂化pyrazolo-triazole化合物2及其有活力的盐显示出了显著的性能.
结论:
- 合成的富含的化能量材料提供了高性能和安全的有前途的组合.
- 化合物2及其能量盐代表了一种新型的热稳定的能量材料.
- 这些发现有助于为未来的应用开发先进的能量材料.
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