相关实验视频
Updated: Jul 5, 2025

07:03
Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
10.7K
来自室温溶解金属纳米集群的近单位NIR光量子产量
Wan-Qi Shi1, Linlin Zeng2, Rui-Lin He1
1Department of Chemistry, Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Tsinghua University, Beijing 100084, P. R. China.
概括
铜注显著提高了溶液中的金纳米团的光发光量子产量 (PLQY). 这一突破使得高排放性金属集群材料可用于先进的应用.
科学领域:
- 材料科学
- 纳米技术
- 摄影化学
背景情况:
- 对金属纳米集群进行近红外 (NIR) 辐射的研究.
- 溶液中的低室温光发光量 (PLQY) (<10%) 限制了它们的应用.
- 开发高辐射NIR材料至关重要.
研究的目的:
- 研究Au22 ((tBuPhCC) 18及其合铜Au16Cu6 ((tBuPhCC) 18的光物理.
- 了解铜剂对光发光特性的影响.
- 在室温下达到接近单一的PLQY溶液.
主要方法:
- 金和金铜合金纳米集群的合成和表征.
- 摄影物理研究,包括在脱气和和溶液中测量PLQY.
- 分析非辐射衰变和系统间交叉速率.
主要成果:
- 在Au22(tBuPhCC) 18中使用铜显著抑制非辐射衰变 (约60倍).
- 铜剂促进了系统间的交叉率 (大约300倍).
- 在室温下,在脱气溶液中达到>99%的PLQY,在氧和溶液中达到61%的PLQY.
- 在720nm观察到的最大排放,尾部为950nm.
结论:
- 铜化是一种有效的策略,可以提高金纳米集群的PLQY.
- 实现接近统一的PLQY为开发先进的发射金属集群材料开辟了道路.
- 这些发现为新型NIR发射应用铺平了道路.
相关概念视频
Photoluminescence: Applications
402
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
402
Variables Affecting Phosphorescence and Fluorescence
504
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
504
Photoluminescence: Fluorescence and Phosphorescence
2.1K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
2.1K

