关闭二拉胺分解 和氧质量平衡:反应性物种途径的最终产品的相对重要性
Huong T Pham1, David G Wahman2, Julian L Fairey1
1Department of Civil Engineering, University of Arkansas, Fayetteville, Arkansas 72701, United States.
Environmental science & technology
|January 18, 2024
概括
在饮用水中的二胺分解可以形成N-二甲基胺 (NDMA). 溶解的氧气影响这些反应,影响和氧气产品的产量和未识别的产品形成.
科学领域:
- 环境化学环境化学
- 水处理 化学 水处理 化学
- 氧化化学 有氧化化学
背景情况:
- 化是一种常见的饮用水消毒方法.
- 单胺自分解可以导致不良副产品的形成.
- 迪拉胺的衰变与N-二甲基胺 (NDMA) 的形成有关.
研究的目的:
- 量化二胺分解中含有和氧的最终产品.
- 研究溶解氧 (DO) 水平对这些反应的影响.
- 评估总二甲基胺 (TOTDMA) 在副产品形成中的作用.
主要方法:
- 在pH9下进行了二拉胺分解实验.
- 用不同的二拉胺度和带/不带TOTDMA进行了反应.
- 实验在环境条件和低溶解氧条件下进行.
主要成果:
- 在环境DO下,的回收量明显低于在TOTDMA存在时的低DO.
- 在环境DO下高度形成的二拉胺分解的未确定的产物,类似于NDMA.
- 这种未确定的产品的形成与过氧酸分解产品与胺反应有关.
结论:
- 溶解的氧气在二胺分解途径和副产品形成中发挥着关键作用.
- NDMA形成和未识别产品生成受DO可用性的影响.
- 对未识别的产品进行核算可以帮助协调这些系统中的和氧质量平衡.
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