对称的DitelluraCalix的合成和研究[6]phyrin(1.1.1.1.1.1) 的s
Md Ashif Ali1, Mangalampalli Ravikanth1
1Indian Institute of Technology Bombay, Powai, Mumbai 400076, India.
The Journal of organic chemistry
|January 18, 2024
概括
合成了新的ditellura calix[6] 氨酸与两个氨酸氨酸氨酸单元. 它们的结构通过X射线和DFT确定,根据替代剂显示出不同的屋顶形状和鸟类形状.
科学领域:
- 宏观循环化学 宏观循环化学
- 有机化合物 有机化合物
背景情况:
- 卡力克斯菲林是具有多种应用的宏环化合物.
- 甲皮林单元具有独特的电子和结构性质.
研究的目的:
- 为了合成新型的Ditellura calix[6]phyrins,这些phyrins中包含了telluratripyrrin部分.
- 研究这些宏观循环的结构多样性.
主要方法:
- 酸催化凝结16-telluratripyrrane与循环子. 酸催化凝结16-telluratripyrrane与循环子.
- 用于结构确定的X射线晶体学.
- 密度函数理论 (DFT) 优化用于结构分析.
主要成果:
- 通过sp3碳连接的两个telluratripyrrin单元成功合成了ditellura calix[6]phyrins.
- 循环基替代衍生物的X射线结构显示了类似屋顶的形状.
- 循环替代衍生物的DFT优化结构表现出类似鸟类的形状.
结论:
- 这种合成扩大了calixphyrin化学的范围.
- 在ditellura calix[6]phyrins中证明了取代剂依赖的形状灵活性.
- 这些发现提供了关于有机纤维宏循环的结构属性关系的见解.
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