聚乙烯微塑料在部分化系统中促进了氧化的产生
Yanying He1, Yingrui Liu1, Xuecheng Li1
1School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, P. R. China.
Environmental science & technology
|January 19, 2024
概括
聚乙烯微塑料 (PVC-MPs) 对部分化 (PN) 废水处理产生负面影响,通过刺激有氧N2O生产和抑制氨氧化率 (AORs) 来增加氧化 (N2O) 排放. 高剂量的PVC-MP显著降低PN的性能.
科学领域:
- 环境科学 环境科学
- 环境工程 环境工程
- 微生物学 微生物学
背景情况:
- 部分化 (PN) 对于侧流系统中高强度废水的处理至关重要.
- PN系统越来越受到微塑料污染的影响,特别是聚乙烯微塑料 (PVC-MPs).
- 了解微塑料对PN的影响对于减轻氧化 (N2O) 排放至关重要.
研究的目的:
- 研究PV-MPs对PN系统中N2O排放通路的影响.
- 量化PVC-MPs对氨氧化率 (AOR) 和N2O生产的影响.
- 阐明PVC-MP诱导的PN性能和N2O排放变化背后的机制.
主要方法:
- 长期实验以评估在不同度的PVC-MP (0.5和5毫克/升) 下的PN性能.
- 批量测试用于测量不同溶解氧水平的AOR和N2O生产率.
- 网站偏好分析和代谢抑制剂,以确定N2O生产途径.
- 对双A出和反应性氧物种 (ROS) 生产的分析.
主要成果:
- 低剂量PVC-MPs (0.5 mg/L) 的影响最小,而高剂量 (5 mg/L) 显著降低了PN性能.
- PVC-MPs降低了AORs的5.78-21.94%并刺激了9.22-88.36%的有氧N2O生产.
- 增加的溶氧减轻了N2O刺激,但恶化了AOR抑制.
- 氧胺氧化和异质脱路径是低DO的N2O增强贡献者.
- 双甲和ROS的产生被确定为导致细胞死亡和社区转移的关键机制.
结论:
- PVC-MPs对PN系统的效率构成重大威胁,并导致N2O排放的增加.
- 微塑料污染是废水处理系统中被低估的一个因素,需要进一步的研究和缓解策略.
- 该研究强调了微塑料,微生物过程和水生环境中的温室气体排放之间的复杂相互作用.
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