伦纳德-斯流体热导率的振动模型:适用范围和准确度水平
1Joint Institute for High Temperatures, Russian Academy of Sciences, 125412 Moscow, Russia.
Physical review. E
|January 20, 2024
概括
一个振动模型解释了液体中的导热性,特别是对于莱纳德-斯系统. 一种结密度缩放方法准确地估计了整个气液相图的热导率.
科学领域:
- 热力学是一种热力学.
- 流体动力学 流体动力学
- 计算物理 计算物理
背景情况:
- 液体中的导热机制仍然不完全理解.
- 一个振动能量转移模型显示,密集液体与柔软相互作用具有前景.
研究的目的:
- 定义液体导热的振动模型的适用范围.
- 使用列纳德-斯系统验证模型的性能.
- 探索冷密度缩放方法用于热导率估计.
主要方法:
- 利用现有的分子动力学模拟结果.
- 应用振动模型进行能量转移分析.
- 使用冷密度缩放方法.
主要成果:
- 振动模型在莱纳德-斯系统的定义适用性领域中表现出部分成功.
- 冷密度缩放方法有效地估计了整个气液相图的热导率,包括超稳定状态.
结论:
- 振动模型为特定系统提供了关于液体导热率的见解.
- 结密度缩放提供了一种可靠的方法,用于在广泛的条件下预测导热率.
相关概念视频
Dimensionless Groups in Fluid Mechanics
339
Dimensionless groups in fluid mechanics provide simplified ratios that help analyze fluid behavior without relying on specific units. The Reynolds number (Re), which represents the ratio of inertial to viscous forces, distinguishes between laminar and turbulent flows, making it essential in the design of pipelines and aerodynamic surfaces. The Froude number (Fr), the ratio of inertial to gravitational forces, is particularly useful in predicting wave formation and hydraulic jumps in...
339
Viscosity of Fluid
421
Viscosity measures the resistance a fluid offers to flow and deformation. It results from internal friction between layers of fluid moving relative to one another. Dynamic viscosity, denoted by the Greek letter mu (μ), quantifies the force needed to move one fluid layer over another. For Newtonian fluids like water and air, the relationship between the shearing stress and the rate of shearing strain is linear, meaning their viscosity remains constant regardless of the applied stress.
421
Heat Capacities of an Ideal Gas II
2.4K
For a system that undergoes a thermodynamic process at a constant volume condition, the heat absorbed is used only to increase the system's internal energy and not for doing any kind of work. While for a system undergoing a thermodynamic process under a constant pressure condition, the amount of heat absorbed is used not only for increasing the internal energy (as a function of temperature) but also for doing some work. The molar heat capacity is the amount of heat required to increase the...
2.4K
Heat Capacities of an Ideal Gas III
2.2K
The number of independent ways a gas molecule can move along straight line, rotate, and vibrate is called its degrees of freedom. Supposing d represents the number of degrees of freedom of an ideal gas, the molar heat capacity at constant volume of an ideal gas in terms of d is
2.2K
Heat Capacities of an Ideal Gas I
2.7K
Heat capacity is the ratio of heat absorbed by the substance corresponding to its temperature change. It is also called thermal capacity and the SI unit of heat capacity is J/K. Whereas, specific heat capacity is defined as the amount of heat necessary to change the temperature of 1 kg of a substance by 1 K and is also called massic heat capacity. Its SI unit is J/kg⋅K.
Molar heat capacity quantifies the ratio of the amount of heat added (or removed) to increase (or decrease) the...
Molar heat capacity quantifies the ratio of the amount of heat added (or removed) to increase (or decrease) the...
2.7K
Thermodynamics: Activity Coefficient
1.5K
Activity is the measure of the effective concentration of the species in solution. It can be expressed as the product of the molar concentration of the species and its activity coefficient. The activity coefficient is a dimensionless quantity and depends on the total ionic strength of the solution.
The activity coefficient is a measure of the deviation from ideal behavior. When the ionic strength of the solution is minimal, the activity coefficient of an ionic species is close to unity, making...
The activity coefficient is a measure of the deviation from ideal behavior. When the ionic strength of the solution is minimal, the activity coefficient of an ionic species is close to unity, making...
1.5K


