溶液中的与结合的有机框架使连续性和高晶体性膜成为可能
Qi Yin1, Kuan Pang1,2, Ya-Nan Feng1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, P. R. China.
Nature communications
|January 20, 2024
概括
结合有机框架 (HOF) 可以分散在溶剂中,形成稳定的状溶液. 这使得能够创建连续的HOF膜,用于高效的气体分离应用.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 化学工程是化学工程的重要组成部分.
背景情况:
- 结合有机框架 (HOFs) 是新兴的多孔材料,其溶液行为研究有限.
- 了解HOF的溶液状态对于开发新的制造方法至关重要.
研究的目的:
- 为了研究HOFs的溶液状态.
- 探索从溶液中制造连续HOF膜的方法.
- 为了评估这些膜的气体分离性能.
主要方法:
- 在溶剂中分散HOF并使用冷电子显微镜,3D电子衍射,1D和2D核磁共振 (NMR) 和泽塔电位分析来表征产生的溶液.
- 通过溶液造方法制造连续的HOF膜.
- 测试HOF膜对C3H6/C3H8混合物的气体分离性能.
主要成果:
- HOFs在溶剂中分裂成小颗粒,同时保持它们的组合.
- 与孤立的分子溶液相比,基于HOF的合溶液表现出明显的分子间相互作用和聚合行为.
- 成功制造了具有高晶度和多孔性的连续HOF膜.
- HOF-BTB@AAO膜显示出高C3H6透率和优异的C3H6/C3H8分离性能 (SF=14).
结论:
- HOF具有独特的解决方案可加工性,使其能够制造连续膜.
- 这些HOF膜提供了一种绿色,低成本和高效的气体分离技术.
- 潜在的应用包括石油裂变和净化过程.
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