在沙平头 (Platycephalus bassensis) 中进行LA-ICP-MS分析的矩阵特定标准的制定
Chun Kit Ooi1, Maxwell Morissette2, Leonid Danyushevsky2
1School of Natural Sciences (Chemistry), University of Tasmania, Locked Bag 1371, Launceston, 7250, Tasmania, Australia.
Environmental pollution (Barking, Essex : 1987)
|January 21, 2024
概括
这项研究开发了激光除诱导合血质谱法 (LA-ICP-MS) 软组织分析的阿加洛斯标准. 这些标准使得可以准确地测量鱼类肌肉中的,揭示了黑色化区域的含量较高.
科学领域:
- 分析化学 分析化学
- 环境科学 环境科学
- 海洋生物学 海洋生物学
背景情况:
- 激光切除感应合等离子体质谱法 (LA-ICP-MS) 对元素分析非常有价值.
- 使用LA-ICP-MS分析软组织是具有挑战性的,因为缺乏用于校准的认证参考材料.
研究的目的:
- 为软组织的LA-ICP-MS分析制定和验证特定矩阵的校准标准.
- 研究沙平头肌中的分布,特别是与黑色化有关.
主要方法:
- 作为实验室制造的标准,准备好的薄糖片.
- 使用1毫米薄的亚加罗斯切片校准LA-ICP-MS (Zn) 分析,将66Zn信号正常化为13C.
- 分析了来自受污染的河口的沙平头的黑色化和非黑色化肌肉组织中的含量.
主要成果:
- 细细的阿加罗斯切片被证明适用于LA-ICP-MS Zn分析鱼类肌肉的校准标准.
- 与非黑色肌肉相比,在黑色肌肉区域发现的度显著更高.
- 非黑色化肌肉区域的含量通常与基线相同,不论黑色化状态如何.
结论:
- 成功开发了LA-ICP-MS软组织分析的特定矩阵标准.
- 开发的标准有助于在环境污染研究中更广泛地应用LA-ICP-MS.
- 鱼类肌肉中的黑色化与积累的增加有关.
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