基于具有不同替代度的奇托-甲基酸联合体的抗氧化剂包装膜的制备,表征和应用
Huimin Yong1, Zeyu Wang1, Jinbao Huang2
1College of Food Science and Engineering, Yangzhou University, Yangzhou 225127, China.
International journal of biological macromolecules
|January 21, 2024
概括
这项研究开发了抗氧化剂包装膜,通过将奇托与甲酸结合. 这些素-甲基酸联体的更高的替代度增强了膜的屏障,机械和抗氧化性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 食品科学 食品科学 食品科学
背景情况:
- 素 (CS) 是一种生物聚合物,具有积极包装应用的潜力.
- 甲酸 (ECG) 是一种强大的抗氧化化合物.
- 开发功能性包装材料需要增强像CS.CS.这样的生物聚合物的特性.
研究的目的:
- 为了合成具有不同替代度的奇托-甲基酸盐 (CS-ECG) 结合物.
- 通过将CS与CS-ECG合物混合,制造抗氧化剂包装膜.
- 为了研究CS-ECG联置换度对薄膜功能的影响.
主要方法:
- 将CS与ECG结合起来,以达到5.18%,6.36%和7.74%的替代度.
- 制造CS/CS-ECG复合薄膜. 在CS/CS-ECG复合膜的制造.
- 使用光谱技术 (UV,1H NMR,FTIR) 进行CS-ECG结合物和CS/CS-ECG膜的表征.
- 评价薄膜的特性,包括水溶性,水接触角度,水蒸气透性,氧透性,抗拉强度,破裂时延长,抗氧化活性和油氧化抑制.
主要成果:
- 与CS相比,CS-ECG结合物表现出降低的结晶性和增强的抗氧化活性.
- CS/CS-ECG膜表现出良好的屏障特性,机械强度以及强大的抗氧化和油氧化抑制能力.
- 含有CS-ECG结合物的膜具有最高的替代度 (7.74%),显示出优越的屏障,机械和抗氧化性能.
结论:
- CS-ECG结合物的替代程度是影响产生的包装膜性质的关键因素.
- 在活性包装应用中,CS-ECG结合物可以有效地增强基托基薄膜的功能.
- 优化CS-ECG结合物的合成可以导致先进的抗氧化剂包装材料.
相关概念视频
Radical Autoxidation
2.1K
The oxidation of an organic compound in the presence of air or oxygen is called autoxidation. For example, cumene reacts with oxygen to form hydroperoxide. Autoxidation involves initiation, propagation, and termination steps. Many organic compounds are susceptible to autoxidation—especially ethers in the presence of oxygen, which form hydroperoxides. Even though this reaction is slow, old ether bottles contain small amounts of peroxide, which leads to laboratory explosions during ether...
2.1K
Preparation of Epoxides
7.7K
Overview
Epoxides result from alkene oxidation, which can be achieved by a) air, b) peroxy acids, c) hypochlorous acids, and d) halohydrin cyclization.
Epoxidation with Peroxy Acids
Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of...
Epoxides result from alkene oxidation, which can be achieved by a) air, b) peroxy acids, c) hypochlorous acids, and d) halohydrin cyclization.
Epoxidation with Peroxy Acids
Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of...
7.7K


