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Updated: Jul 5, 2025

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents

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基 (II) 和基 (II) 和基 (III) 复合物与酸盐组:光学特性和光催化

David Gómez de Segura1, Andrea Corral-Zorzano1, Eduardo Alcolea1

  • 1Departamento de Química, Instituto de Investigación en Química (IQUR), Complejo Científico Tecnológico, Universidad de La Rioja, Madre de Dios 53, Logroño 26006, Spain.

Inorganic chemistry
|January 22, 2024
PubMed
概括

这项研究合成了具有独特光物理性质的复合物. 复合体3a产生单点氧,表明光催化作用的潜力.

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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst09:12

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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相关概念视频

Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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