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研究表面活性剂修改的地质聚合物凝的固化和泡,基于煤炭燃烧的灰和渣渣废物
Elena A Yatsenko1, Sergei V Trofimov1, Boris M Goltsman1
1Department "General Chemistry and Technology Silicates", Platov South-Russian State Polytechnic University (NPI), Prosveshcheniya Street 132, Rostov Region, 346428 Novocherkassk, Russia.
Gels (Basel, Switzerland)
|January 22, 2024
概括
优化地质聚合物凝特性需要仔细考虑固化条件和材料组成. 酸和烤箱固化产生了优越的强度和密度,为可持续的材料开发提供了节能替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 可持续材料 可持续材料
背景情况:
- 地质聚合物凝是具有多孔地质聚合物特性的泡构成.
- 了解固化影响是优化地质聚合物凝特性的关键.
研究的目的:
- 研究温度-时间,表面活性剂和废物成分对地质聚合物凝固化的影响.
- 为了确定增强地质聚合物凝性能的最佳条件.
主要方法:
- 探索各种温度-时间固化条件.
- 评估不同的废物成分和表面活性剂的影响 (酸).
- 传统的烤箱固化与微波固化的比较.
主要成果:
- 12小时的固化期在6小时内提供了显著的改善,在24小时内获得了最小的收益,这表明了能源效率.
- 酸显著提高了地质聚合物凝强度.
- 微波固化产生低密度,但由于杜马斯反应,不适合在高温 (>200°C) 上酸.
- 用酸和烤箱固化实现了最佳性能,达到1.08 MPa和1.17 MPa的强度.
结论:
- 量身定制的固化方法,特别是用酸烤箱固化,对于最大限度地提高地质聚合物凝特性至关重要.
- 虽然微波固化节能,但必须仔细评估材料的兼容性.
- 这项研究为开发具有增强性能的可持续地质聚合物材料提供了洞察力.
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