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从Citrullus colocynthis种子油制备生物基聚氨涂层:特征和腐蚀性能

Ahmed S Alshabebi¹, Maher M Alrashed¹, Lahssen El Blidi¹

¹Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia.

|January 23, 2024

概括

从Citrullus colocynthis种子油 (CCSO) 开发了一种新的环氧化油,用于聚氨涂层. 这种生物基聚醇在先进的涂料应用中显示出有前途的特性.

科学领域:

材料科学材料科学材料科学
聚合物化学聚合物化学
绿色化学绿色化学

背景情况:

聚氨 (PU) 涂料被广泛使用,但通常依赖于以石油为基础的原料.
涂料行业对可持续和生物基替代品的需求越来越大.
黄色合金种子油 (CCSO) 是一种未充分利用的脂肪酸来源,用于化学修饰.

研究的目的:

来自CCSO的新型环氧化油的合成和表征.
通过氧化CCSO的氧化产生生物基聚.
制定和评估由合成的生物基聚来制造的聚氨涂层.

主要方法:

使用气体染色体质谱法 (GC-MS) 分析CCSO的脂肪酸概况.
使用现场生成的酸氧化CCSO.
环氧化CCSO的氧化,形成一个生物基聚合物.
使用FT-IR和1HNMR光谱学对中间体和聚醇进行表征.
使用生物基聚合物和3HDI异酸盐的PU涂层的配方.
评估PU涂层特性 (硬度,粘附性,光泽性,耐化学物质,EIS).

主要成果:

成功合成了环氧化CCSO和随后的生物基聚合物.
FT-IR和1H NMR证实了合成材料的功能组.
由此产生的PU涂层表现出良好的性能,包括良好的硬度,粘合力和耐化学物质.
电化学阻抗光谱 (EIS) 显示了涂层的潜在保护能力.

结论:

氧化CCSO是一种可行的前体,可用于生产生物基聚醇.
合成的聚醇可以有效地用于制造高性能聚氨涂层.
来自CCSO的PU涂料为各种涂料应用提供了一个有希望的可持续替代品.

关键词:

在这种情况下,Citrullus的颜色会变色.抗腐蚀的方法抗腐蚀的方法氧化时发生氧化作用.聚聚烯的多元化聚氨是一种聚氨.可再生能源是可再生能源.表面涂层是一种表面涂层.

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