大气压等离子体喷射暴露聚乳酸表面的更好的粘附:等离子体参数对聚合物特性
Andrei Vasile Nastuta1, Mihai Asandulesa2, Florica Doroftei2
1Physics and Biophysics Education Research Laboratory (P&B-EduResLab), Biomedical Science Department, Faculty of Medical Bioengineering, "Grigore T. Popa" University of Medicine and Pharmacy Iasi, M. Kogalniceanu Str., No. 9-13, 700454 Iasi, Romania.
Polymers
|January 23, 2024
概括
大气压等离子处理提高了聚乳酸 (PLA) 表面的湿透性,并改变了化学成分. 这种环保方法可以改善PLA,用于需要更好的粘合力的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 聚合物科学 聚合物科学
背景情况:
- 聚合物在工业中至关重要,但表面修改通常是必要的.
- 可生物降解的聚乳酸 (PLA) 由于机械性能差,在生物医学用途上存在局限性.
- 非热等离子体提供了一个环保的表面修饰技术.
研究的目的:
- 为了研究大气压等离子体对聚乳酸 (PLA) 表面的影响.
- 分析PLA的湿透性,化学成分和表面性能的变化.
- 评估血治疗对增强PLA特性的潜力.
主要方法:
- 使用介电屏障放电系统,使用 (He) 和/或 (Ar) 产生大气压等离子体.
- 暴露的多乳酸 (PLA) 样本,以适应量身定制的血条件.
- 分析了表面的湿透性,地形,形态,粗性,化学成分,介电性质,相位过渡和结构.
主要成果:
- 血处理显著提高了PLA表面的可湿性 (高达40%的He,20%的Ar).
- 观察到表面地形,形态,粗度和水友性的变化.
- 检测到聚合物的介电特性,相位过渡和结构的修改.
结论:
- 大气压等离子处理是修改PLA表面的有效和环保方法.
- 等离子处理提高了PLA的湿透性,改变了表面特性,使其适用于需要增强粘合力的应用.
- 这项技术支持可持续的聚合物加工,以满足专门的工业需求.
相关概念视频
Hydrogen Bonds
Hydrogen BondsHydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.Hydrogen Bonds Control the World!Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are...
Adsorption of Gases on Solids
Adsorption is a process where molecules, known as the adsorbates, accumulate on a surface, which is referred to as the adsorbent or substrate. Occurring at the solid-gas interface, this phenomenon is crucial in various scientific and industrial contexts. The reverse of adsorption is desorption.Two types of adsorptions exist: physical (physisorption) and chemical (chemisorption). Physisorption involves gas molecules held to the solid's surface by relatively weak intermolecular van der Waals...
Intermolecular Forces
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Intermolecular Forces and Physical Properties
Colloidal precipitates
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Cohesion
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a surface,...
On a surface,...


