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基于生物聚合物的热性能聚氨泡的制造,具有绝热应用

Pedro Luis De Hoyos-Martinez¹, Sebastian Barriga Mendez¹, Eriz Corro Martinez²

¹Chemical and Environmental Engineering Department, University of the Basque Country, Plaza Europa 1, 20018 Donostia-San Sebastián, Spain.

|January 23, 2024

概括

新的生物基刚性聚氨泡 (PUFs) 使用木材残留物和阻燃剂提供卓越的绝热和耐火性,符合工业标准.

科学领域:

材料科学材料科学材料科学
聚合物化学聚合物化学
可持续材料可持续材料

背景情况:

聚氨泡 (PUF) 广泛使用,但通常依赖于合成,不可再生的聚合物.
对于具有竞争力的热和防火性能的可持续材料的需求越来越大.
阻燃剂对于提高PUF的消防安全至关重要.

研究的目的:

使用木材残留物衍生的生物聚合物开发基于生物的刚性PUF.
评估多面性寡合性丝素 (POSS) 和氨基聚酸盐 (APP) 阻燃剂对PUF特性的影响.
为了比较生物基PUF与商业产品的绝热和防火性能.

主要方法:

从木材残留物中合成生物聚合物,通过扩大规模的工艺.
生物基PUF的配方,含有不同数量的POSS和APP阻燃剂.
使用富里埃变形红外光谱 (FTIR) 和热重力测量分析 (TGA) 进行了表征.
通过UL-94垂直燃烧试验和限制氧气指数 (LOI) 评估火力性能.

主要成果:

合成的生物聚合物完全取代了PUF配方中的合成聚合物.
增加POSS和APP提高了UL-94和LOI等级,提高了耐火性.
生物基PUF表现出优异的热绝缘 (0.02371-0.02149 W·m−1·K−1),略高于工业PUF.
生物基配方的防火性能与工业基准相当.

结论:

生物基刚性PUF可以使用木材衍生生物聚合物成功开发.
整合POSS和APP阻燃剂显著提高了这些生物基材料的消防安全.
开发的生物基PUF提供了具有竞争力的隔热和防火性能,为传统PUF提供了可持续的替代品.

关键词:

生物聚合物生物聚合物防火防火防火防火防火无机填充剂是一种无机填充剂.聚氨是一种聚氨.热绝缘体的热绝缘体可以使用.

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