废水表征:化学氧气需求还是总有机碳含量测量?
László Wojnárovits1, Renáta Homlok1, Krisztina Kovács1
1HUN-REN Centre for Energy Research, Konkoly-Thege M. út 29-33, 1121 Budapest, Hungary.
Molecules (Basel, Switzerland)
|January 23, 2024
概括
这项研究研究了化学氧气需求 (COD) 和个人化学品的总有机碳 (TOC) 之间的关系. 结果显示,分子结构对COD/TOC比率产生影响,需要化学特异性相关性才能进行准确的废水分析.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 废水处理 废水处理
背景情况:
- 标准的化学氧气需求 (COD) 测量是耗时的,昂贵的,并使用有毒试剂.
- 总有机碳 (TOC) 正在越来越多地取代COD,但污染极限通常仍然在COD中.
- 对于单个化学污染物,需要COD和TOC之间的相关性.
研究的目的:
- 调查70个单个化学污染物的COD和TOC之间的相关性.
- 为了确定各种化学品类的COD/TOC比率.
- 评估TOC作为废水分析中COD的替代品的适用性.
主要方法:
- 计算了70种污染物的理论COD值.
- 计算的COD与实验值的比较.
- 基于分子结构的COD/TOC比率的分析.
主要成果:
- 计算的COD值通常在与实验值约10%的范围内达成一致.
- 环素和一些芳香化合物在实验中显示COD比计算低20-50%.
- COD/TOC比率在2和3之间变化,其中宏类 (~3) 和诺基诺/四环素 (~2) 的具体值.
结论:
- 由于COD/TOC比率取决于分子结构,因此需要个别化学物质的特定相关性.
- 在先进的氧化过程中,COD/TOC比率的变化限制了TOC直接替代COD的可能性.
- 准确的废水分析需要了解不同污染物的COD和TOC之间的特定关系.
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