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APTES作为聚乙烯涂层AA2024-T3 Primer 的作用

John Halford¹, Cheng-Fu Chen¹

¹Department of Mechanical Engineering, University of Alaska Fairbanks, Fairbanks, AK 99775-5905, USA.

|January 23, 2024

概括

(3-Aminopropyl) triethoxysilane (APTES) 增强了合金对腐蚀的保护作用. 优化的APTES原料和聚烯顶层显著提高了稳定性和性能,特别是在热处理方面.

科学领域:

材料科学材料科学材料科学
腐蚀科学腐蚀科学
表面化学表面化学

背景情况:

(3-阿米诺) 三基西兰 (APTES) 作为有机和无机材料之间的关键接口.
合金AA2024-T3需要有效的表面保护,以提高耐用性.
基于西兰的原料被用作各种应用中的粘附剂和表面修饰剂.

研究的目的:

调查APTES作为AA2024-T3防腐蚀防护原料的作用.
评估APTES沉积时间和后处理对涂层性能的影响.
了解APTES原料和聚乙烯 (PS) 上层之间的相互作用.

主要方法:

在AA2024-T3.3.上进行APTES蒸汽沉积的组合实验.
电化学阻抗光谱 (EIS) 用于对腐蚀性能进行评估.
通过接触角度分析和扫描电子显微镜 (SEM) 测量表面能量.

主要成果:

在40分钟的时间内,APTES采用后热处理和PS顶层进行了40分钟的原始化,显示出出色的腐蚀阻抗.
APTES原料表面的更高的表面能量与腐蚀阻抗的增加相关.
更薄的APTES原料 (20分钟) 提供了由于水解稳定性和氧化物溶解的早期保护.

结论:

APTES/PS涂层系统提供了卓越的保护,由于PS在更高表面能量的APTES Primer上增强了PS的湿透性.
热处理显著增加了APTES原料涂层系统的阻抗.
APTES和类似的西兰酸具有广泛的潜在应用,作为微型设备及其他领域的表面修饰剂.

关键词:

在AA2024-T3中使用.他们的胃口.涂层涂层是一种涂层.腐蚀腐蚀是一种腐蚀.电化学阻抗光谱学电化学阻抗光谱学聚乙烯是一种聚乙烯.这是一个非常好的初级初级初级.锡拉尼斯 (silanes) 是一种制剂.表面能量是表面的能量.蒸汽沉积蒸汽沉积的情况

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