在生物固体中识别微塑料的ATR-FTIR和NIR光谱的比较
Luana Circelli1, Zhongqi Cheng2, Evan Garwood3
1Department of Agricultural, Environmental and Food Sciences, University of Molise, Campobasso, Italy; Department of Earth and Environmental Sciences, Brooklyn College of the City University of New York, Brooklyn, NY, USA.
The Science of the total environment
|January 23, 2024
概括
本研究使用光谱学识别生物固体中的微塑料 (MP). 研究发现,MP通常来自消费者包装和洗衣纤维,主要由聚乙烯组成.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 微塑料 (MP) 是农业土壤中令人担忧的新兴污染物.
- 生物固体是MP进入陆地生态系统的重要潜在来源.
研究的目的:
- 为了确定生物固体样本中发现的MPs的聚合物起源.
- 为了比较减弱总反射-里叶变换红外光谱 (ATR-FTIR) 和近红外光谱 (NIR) 对于MP识别的有效性.
主要方法:
- 从生物固体样本中提取MPs并进行光谱分析 (ATR-FTIR和NIR).
- 将光谱数据与52种选定的商业塑料 (SCP) 材料库进行比较.
- 使用Savitzky-Golay (SG) 和第一导数 (FD) 方法进行光谱预处理.
主要成果:
- 生物固体中的MP显示出与聚乙烯 (LDPE,HDPE),PET,PS,PP和PA的高光谱相关性.
- 大多数议员被确定为LDPE/HDPE (相关系数>0.90).
- 在识别PP和PET方面,NIR光谱更有效,而ATR-FTIR在识别PS方面更好.
结论:
- 生物固体中MP的主要来源可能是废弃的消费包装和与洗衣相关的纤维.
- ATR-FTIR和NIR光谱是可行的,快速的方法,用于识别MPs复杂的矩阵,如生物固体.
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