对于时间依赖和随机扰动的准确响应理论
Leonardo Iannella1, Lamberto Rondoni2,3
1Dipartimento di Fisica, Università di Torino, Via Pietro Giuria 1, 10125 Torino, Italy.
Entropy (Basel, Switzerland)
|January 26, 2024
概括
这项研究扩展了准确响应理论,包括依赖时间的随机扰动. 采用卡鲁宁-洛埃夫定理的增强理论,提供了分析复杂动态系统的新方法.
科学领域:
- 非平衡的统计力学.
- 理论物理学的理论物理.
- 计算化学是一种计算化学.
背景情况:
- 非平衡分子动力学 (NEMD) 提供了准确的反应理论.
- 过渡时间相关函数 (TTCF) 是一个关键元素,量化消散功率.
- 现有的理论处理决定性系统中的时间独立和依赖性扰动.
研究的目的:
- 将时间依赖的随机扰动纳入准确响应理论.
- 将TTCF的适用性扩展到具有随机影响的系统.
- 为分析不能接受线性响应理论的系统提供框架.
主要方法:
- 卡鲁宁-洛耶夫定理应用于随机过程.
- 开发了三种不同的平均化方案,用于随机扰动.
- 对具有初始条件和随机系数变化的动态系统进行分析.
主要成果:
- 概括理论适应了时间依赖的随机扰动.
- 对于随机过程,提出了三种新的调查方法.
- 在扩展的理论框架中,散射函数仍然是核心.
结论:
- 增强的精确响应理论适用于更广泛的动态系统.
- 随机性的包含为系统行为提供了更深入的见解.
- 该理论的实用性通过说明性示例来证明.
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