全能量材料立方左聚:等离子体合成和热性能
Chenxi Qu1,2, Jiale Li1, Kewei Ding1
1Xi'an Modern Chemistry Research Institute, Xi'an 710065, China.
Molecules (Basel, Switzerland)
|January 26, 2024
概括
合成了高能材料聚,并分析了其热分解. 立方聚 (cg-N) 具有良好的热稳定性,分解温度为429°C.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 能量材料 能量材料
背景情况:
- 理论计算表明,聚是超高能材料.
- 已经实现了立方 gauche 聚化 (cg-N) 的合成,但其热性能尚不清楚.
研究的目的:
- 使用涂层基板合成宏观的多样品.
- 研究cg-N.的热分解行为和稳定性.
主要方法:
- 用碳纳米管增强的等离子体化学蒸汽沉积 (PECVD).
- 使用IR,拉曼,XRD,XPS和TEM进行表征.
- 热分析包括DSC,TG-DSC-FTIR-MS和动力分析 (基辛格,奥扎瓦方程).
主要成果:
- 使用涂层基板成功合成了宏观cg-N样本,提高了产量.
- 沉积聚的结构被证实为cg-N.
- 确定cg-N的热分解温度为429°C.
- 表面激活能量 (Ea) 计算为84.7kJ/mol (Kissinger) 和91.9kJ/mol (Ozawa) 的值.
结论:
- cg-N 是一种具有良好的热稳定性的全材料.
- cg-N显示了在高能量密度材料中的应用潜力.
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