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Updated: Jul 4, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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合成,晶体结构,光谱和计算研究NLO活性2-methylimdazolium4-nitrobenzoic酸单晶的研究

Anbu Gopalakrishnan1, Chinnasami Sidden2, Sivanandam Magudeeswaran3

  • 1R&D Laboratory, Department of Physics, Sri Shanmugha College of Engineering and Technology (Autonomous), Sankari-637304, Tamilnadu, India.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
|January 26, 2024
PubMed
概括

本研究研究了有机晶体2-Methylimidazolium 4-Nitrobenzoic Acid (2MI4NB),证实了其三临床结构,并使用实验和理论方法探索了其非线性光学 (NLO) 特性.

关键词:
晶体结构 晶体结构水素键是一种键.超极化性 超极化性有机晶体有机晶体采用Z扫描进行扫描.

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Structure of Carboxylic Acid Derivatives
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Naming Amides
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The hybridized nitrogen atom in amines possesses a lone pair of electrons and is bound to three substituents with a bond angle of around 108°, which is less than the tetrahedral angle of 109.5°. However, the C–N–H bond angle is slightly larger at 112°, with a carbon–nitrogen bond length of 147 pm. This carbon–nitrogen bond length of of amines is longer than the carbon–oxygen bond of alcohols (143 pm) but shorter than alkanes’...
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Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.
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