甲基硫酸盐在混合溶液中的Kraft点以下的可溶性提高
Veronika I Yavrukova1, Krassimir D Danov1, Tatiana G Slavova1
1Department of Chemical & Pharmaceutical Engineering, Faculty of Chemistry & Pharmacy, Sofia University, Sofia 1164, Bulgaria.
Journal of colloid and interface science
|January 27, 2024
概括
甲基硫酸盐 (MES) 的溶解性在阳离子表面活性剂小粒中得到改善. 研究表明,相图和模型有助于预测与AOS和SLES-2EO表面活性剂混合物的MES溶解度.
科学领域:
- 物理化学 物理化学
- 合体和表面科学科学
背景情况:
- 甲基硫酸盐 (MES) 在克拉夫特点以下具有有限的水溶性.
- 将MES纳入阳离子表面活性剂小粒中可以提高溶解度.
- 带电小粒内的静电相互作用显著影响MES溶解度.
研究的目的:
- 调查MES在二进制和三进制混合物中与阳离子表面活性剂的可溶性.
- 在低温下建立MES-表面活性剂混合物的相位图.
- 开发和验证离子表面活性剂混合物相位分离的理论模型.
主要方法:
- 在5°C测量了MES与α烯硫酸盐 (AOS) 和劳利乙烯硫酸盐 (SLES-2EO) 的溶解性和电解导电性.
- 对二元和三元表面活性剂混合物的构建相位图.
- 开发并通过实验验证了一种一般相位分离理论模型.
主要成果:
- 已识别的相域包括混合微粒,微粒+晶体,晶体和分子溶液.
- 该理论模型准确地预测复杂的相位图,并提供组件度和微粒电静电潜力.
- 确定了MES在透明微粒溶液中的最大摩尔分数.
结论:
- 开发的相分离模型对于复杂的离子表面活性剂混合物是有效的.
- 了解相位行为可以提高基于MES的表面活性剂的适用性.
- 该研究提供了对优化MES在表面活性剂配方中的溶解度的见解.
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