超强硬的聚乳酸/生物基聚氨混合物的现场自交联策略
Tao Shou1, Yaowen Wu1, Dexian Yin1
1State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, China.
International journal of biological macromolecules
|January 28, 2024
概括
这项研究通过现场聚合增强了使用生物基聚氨 (PO3G-PU) 的聚乳酸 (PLA) 性. 由此产生的混合物提供了更好的刚性和性,减少了对石化产品的依赖.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续材料 可持续材料
背景情况:
- 聚乳酸 (PLA) 是一种广泛使用的生物塑料,但其脆性阻碍了应用.
- 提高PLA性通常涉及现场聚合,但在聚氨 (PU) 和依赖石油原料方面仍然存在挑战.
研究的目的:
- 开发一种基于生物的PLA硬化策略,使用现场自交联聚氨.
- 调查 1,3-多二醇 (PO3G) 作为可持续的替代聚的使用.
- 为了在PLA/PO3G-PU混合物中实现刚性和性之间的平衡.
主要方法:
- 通过在现场的自我交叉连接策略来制备PLA/PO3G-PU混合物.
- 使用生物基的1,3-多二醇 (PO3G) 而不是传统的多,如PEG或PPG.
- 机械性能的表征,包括口冲击和拉伸强度.
主要成果:
- PLA/PO3G-PU混合物表现出明显提高的性,其口冲击强度为55.95kJ/m2.
- 拉力强度达到了47.77MPa,保持了纯PLA强度的68.9%.
- 这些混合物在刚性和性之间取得了有利的平衡.
结论:
- 使用PO3G-PU的现场自交联策略有效地提高了PLA的性.
- 这种方法提供了一个可持续的替代品,以石油化工为基础的硬化方法为PLA.
- 开发的PLA/PO3G-PU混合物为实现生物基塑料的刚性-性平衡提供了一个可行的选择.
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