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相关概念视频

Turnover Number and Catalytic Efficiency01:19

Turnover Number and Catalytic Efficiency

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The turnover number of an enzyme is the maximum number of substrate molecules it can transform per unit time. Turnover numbers for most enzymes range from 1 to 1000 molecules per second. Catalase has the known highest turnover number, capable of converting up to 2.8×106 molecules of hydrogen peroxide into water and oxygen per second. Lysozyme has the lowest known turnover number of half a molecule per second.
Chymotrypsin is a pancreatic enzyme that breaks down proteins during digestion....
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Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes02:14

Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes

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The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were  initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
6.4K
Enthalpy and Heat of Reaction02:12

Enthalpy and Heat of Reaction

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Combustion, commonly known as burning, is a reaction in which a substance reacts with an oxidizing agent, which in most cases is molecular oxygen, to liberate energy in the form of heat, light, or sound. The heat of combustion is also known as the enthalpy of combustion. The energy released when one mole of a substance undergoes complete combustion at constant pressure is called molar heat of combustion. Combustion reactions are exothermic; that is, they release energy, and their ΔH sign...
8.4K
Otto and Diesel Cycle01:27

Otto and Diesel Cycle

1.7K
An Otto engine is a four-stroke engine that uses a mixture of gasoline and air as the working fuel. The fuel is injected into the cylinder, and the piston is moved completely down so that the cylinder is at maximum volume. By moving the piston up, adiabatic compression takes place. The spark plug ignites the gasoline-air mixture, and the burning fuel adds heat to the system at a constant volume. The heated mixture expands adiabatically and gets further cooled by exhausting heat, and this cyclic...
1.7K
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

10.2K
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

10.4K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
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氧化燃料的燃烧使得碳捕获更加有效.

Saeed Talei1, Daniel Fozer2, Petar Sabev Varbanov3

  • 1Institute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.

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概括
此摘要是机器生成的。

与空气燃烧相比,氧化燃料的燃烧大大降低了碳捕获的能源需求,节省了高达84%的能源,并捕获了100%的碳. 这种方法还可以防止氧化的形成.

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科学领域:

  • 化学工程是化学工程的重要组成部分.
  • 环境科学 环境科学
  • 能源技术 能源技术 能源技术

背景情况:

  • 化石燃料仍然是必不可少的,需要排放控制策略.
  • 碳捕获和利用对于满足环境法规至关重要.
  • 氧化燃料燃烧为减少排放提供了传统空气燃烧的替代方案.

研究的目的:

  • 为了比较空气和氧燃料燃烧之间的碳捕获效率和能源需求.
  • 评估来自各种工业来源的烟气中的碳捕获.
  • 评估氧燃料技术对温室气体减排的可行性.

主要方法:

  • 使用ASPEN Plus进行数学建模.
  • 使用单乙胺溶剂对碳捕获的模拟.
  • 对五种工业烟气流 (天然气发电,煤电,热电联合,,水泥) 的比较分析.

主要成果:

  • 氧化燃料的燃烧需要的碳捕获能量要少得多,尤其是在高去除率 (>90%) 的情况下,节省了高达84%的能量.
  • 100%的二氧化碳捕获是可以通过氧燃料燃烧实现的.
  • 氧化燃料烟气中较高的二氧化碳度提高了质量转移和捕获效率.

结论:

  • 氧化燃料的燃烧比空气的燃烧提供了比碳捕获更节能的方法.
  • 该技术在各种工业排放源中有效.
  • 氧化燃料的燃烧消除了氧化的形成,提供了额外的环境效益.