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Updated: Jul 4, 2025

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在聚乙烯糖醇水溶液中汉奇二胺合成中的分子拥挤效应

Akihisa Miyagawa1, Yasuyuki Ueda2, Kiyoharu Nakatani1

  • 1Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.

Physical chemistry chemical physics : PCCP
|January 30, 2024
PubMed
概括

分子拥挤会影响反应速率. 聚乙烯甘醇 (PEG) 最初增加了汉奇胺反应速率常数,但较高的PEG度降低了它,这是由于对立的透和体积排除效应.

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