电气双层电容和伪电容的可控制合成,与离子混合电容器的多孔碳阴极材料相结合
Xiaoyi Pan1, Qian Li1, Tongde Wang2
1College of Materials Science and Engineering, Sichuan University, Chengdu, 610065, People's Republic of China. taoys@scu.edu.cn.
Nanoscale
|January 31, 2024
概括
具有优化孔径和氧气组的工程碳材料提高了离子混合电容的性能. 这种设计增强了离子可访问性和动力学,为优越的能量存储和长期稳定性提供了优势.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 碳材料对离子混合电容器 (ZIHC) 是有前途的,因为它们的多孔结构.
- 碳中的微孔封闭阻碍了离子动力学,这是一个尚未完全解决的挑战.
- 优化毛孔结构对于提高ZIHC性能至关重要.
研究的目的:
- 设计一个可控制孔径的大小的碳材料,以提高ZIHC中的离子可访问性.
- 调查孔径大小,缺陷和功能组对离子转移和伪电容的影响.
- 阐明ZIHC中电化学性能改善背后的机制.
主要方法:
- 合成可控制孔径的大小的碳材料.
- ZIHCs的电化学表征 (性能测试).
- 实验和第一原则计算 (包括现场分析).
主要成果:
- 适当的孔径和缺陷可以增强离子转移和吸附.
- 含有氧的功能组引入有益的伪容量.
- 设计的材料实现了高功率密度 (9.9千瓦千克-1),能量密度 (100瓦时千克-1),以及出色的循环稳定性 (在5万个循环后保持93%).
结论:
- 优化的孔隙工程和功能化是克服碳基ZIHC的动力限制的关键.
- 由氧组驱动的电双层电容 (EDLC) 和伪电容机制,支了卓越的性能.
- 这项研究为快速离子存储的先进碳电极材料提供了一个强大的设计策略.
相关概念视频
Capacitor With A Dielectric
3.9K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
3.9K
MOS Capacitor
782
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
782
Dielectric Polarization in a Capacitor
4.7K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.7K
Capacitors and Capacitance
7.6K
A device consisting of two electrical conductors that are separated by a distance and used to store electrical charges is called a capacitor. The space between the conductors is either a vacuum or an insulating material, called a dielectric. Capacitors have many applications, ranging from filtering static from radio reception to energy storage in heart defibrillators.
When the conductors are two identical parallel plates, it is called a parallel plate capacitor. When battery terminals are...
When the conductors are two identical parallel plates, it is called a parallel plate capacitor. When battery terminals are...
7.6K
Spherical and Cylindrical Capacitor
5.7K
A spherical capacitor consists of two concentric conducting spherical shells of radii R1 (inner shell) and R2 (outer shell). The shells have equal and opposite charges of +Q and −Q, respectively. For an isolated conducting spherical capacitor, the radius of the outer shell can be considered to be infinite.
Conventionally, considering the symmetry, the electric field between the concentric shells of a spherical capacitor is directed radially outward. The magnitude of the field,...
Conventionally, considering the symmetry, the electric field between the concentric shells of a spherical capacitor is directed radially outward. The magnitude of the field,...
5.7K
Capacitors
432
Capacitors play a crucial role in car radios, where they filter and store frequencies to ensure clear signal reception. Essentially serving as energy storage devices, capacitors store energy within their electric field and are composed of two parallel conducting plates separated by a dielectric.
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
432


