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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

27.4K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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DC Battery01:21

DC Battery

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A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Ionic Compounds: Formulas and Nomenclature03:34

Ionic Compounds: Formulas and Nomenclature

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An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Voltaic/Galvanic Cells02:47

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Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
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相关实验视频

Updated: Jul 4, 2025

A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery
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A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery

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一个可充电的Ca/Cl2电池

Shitao Geng1, Xiaoju Zhao1, Qiuchen Xu1

  • 1Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, and Zhangjiang Institute for Advanced Study, Shanghai Jiao Tong University, 200240, Shanghai, China.

Nature communications
|January 31, 2024
PubMed
概括
此摘要是机器生成的。

研究人员开发了一种新的可充电- (Ca/Cl2) 电池. 这种可持续的储能解决方案提供了高容量,优异的保留和低温性能,克服了Ca金属电池以前的局限性.

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Dynamic Electrochemical Measurement of Chloride Ions
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科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 可持续的能源储存 可持续的能源储存

背景情况:

  • 可充电的 (Ca) 金属电池提供可持续的能量储存,因为Ca丰富.
  • 当前Ca电池的局限性包括能量/功率密度低,容量保留差,低温性能有限.

研究的目的:

  • 开发一种实用的可充电Ca金属电池,克服现有的局限性.
  • 引入一种新的Ca/Cl2电池化学,利用可逆氧化还原反应.

主要方法:

  • 设计了一个可充电的Ca/Cl2电池系统.
  • 使用二酸作为一个电解质介质.
  • 研究了CaCl2和Cl2.2之间的可逆阴极氧化还原反应.

主要成果:

  • 实现了3V的放电电压.
  • 证明了显著的特定容量 (1000 mAh g-1) 和速率能力 (500 mA g-1).
  • 展现出出色的容量保留 (96.5%在30天后) 和低温性能 (低至0°C).

结论:

  • 开发的Ca/Cl2电池解决了可充电Ca金属电池的主要瓶问题.
  • 这一进步为高性能,可持续的基于的能量存储铺平了道路.