基于Viologen的离子联介孔聚合物作为高效聚硫化物捕获和转换的电子传送器
Hai-Yang Li1, Zhong-Shan Li1, Gang-Hao Qiu1
1Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Key Laboratory of Special Environmental Functional Materials (Zhengzhou University), Ministry of Education, Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China.
Science bulletin
|February 1, 2024
概括
一种基于viologen的新型聚合物有效地减轻了硫 (Li-S) 电池中的穿效应. 这种阴极修改增强了聚硫化物吸附和转化,使稳定的循环和高效的先进的Li-S能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫 (Li-S) 电池的商业化受限于聚硫化物穿效应和缓慢的氧化还原动力学.
- 开发有效的阴极主机对于提高Li-S电池性能至关重要.
研究的目的:
- 开发一种用于Li-S电池的新型阴极主体材料.
- 为了解决穿效应,并提高Li-S电池的电化学性能.
主要方法:
- 一种基于viologen的离子结合的中性聚合物 (TpV-Cl) 的合成.
- 使用合成聚合物作为宿主材料对Li-S电池阴极的修改.
- 电化学表征包括循环性能和库伦比效率.
主要成果:
- 阴极S@TpV-PS表现出极好的循环稳定性,在2.0°C完成300个循环,衰变速率低 (每周期为0.032%).
- 使用S@TpV-PS实现了高硫负载 (4.0 mg cm-2),保持了出色的循环稳定性和高达98%的库伦比克效率.
- 素成分作为可逆电子输送器,提高了聚硫化物吸附和转化率.
结论:
- 开发的基于viologen的聚合物 (TpV-Cl) 显示出作为高性能Li-S电池的阴极主体的巨大潜力.
- 该材料有效地抑制了穿效应,并增强了氧化还原动力学,从而提高了电池的寿命和效率.
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