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相关概念视频

Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.0K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.0K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.6K
Solubility Equilibria03:07

Solubility Equilibria

52.7K
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation.
The...
52.7K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.3K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.3K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

63.2K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
63.2K
Acid Halides to Alcohols: LiAlH4 Reduction01:19

Acid Halides to Alcohols: LiAlH4 Reduction

2.8K
Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
2.8K

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相关实验视频

Updated: Jul 4, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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对于全固态电池的高湿度耐受固态电解质.

Kai Wang1,2, Zhenqi Gu2, Haoxuan Liu3

  • 1School of Materials & Energy, Lanzhou University, Lanzhou, Gansu, 730000, China.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|February 2, 2024
PubMed
概括

这项研究引入了一种新的基化固态电解质,可以克服全固态电池 (ASSLB) 中的水分问题. 这种新型电解质为实际的ASSLB应用提供了更好的离子导电性和稳定性.

关键词:
不同价值的替代替代.所有固态电池都是固态电池.化物固态电解质的固态电解质.耐受性湿度 耐受性湿度

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques

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相关实验视频

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 化物固态电解质 (SSEs) 对于全固态电池 (ASSLB) 是至关重要的.
  • 目前以基化物为基础的SSEs面临诸如湿度敏感性,低导电性和低热稳定性等挑战,阻碍了ASSLB的商业化.

研究的目的:

  • 为了开发一种新的基基固态电解质,添加的基.
  • 解决现有的化物SSE的局限性,提高ASSLB的性能.

主要方法:

  • 制造基化物 (hc-Li2+xZr1-x在xCl6) 的化物.
  • 离子导电性,热稳定性和湿透可逆性的表征.
  • 使用新型电解质组装和测试全固态电池 (ASSLBs).

主要成果:

  • 新型hc-Li2+xZr1-xInxCl6表现出增强的离子导电性 (高达1.4mS cm-1) 和热稳定性 (350°C).
  • 在暴露于湿度和热处理后,已经证明了显著的湿度可逆性 (82.5%的恢复).
  • 用电解质组装的ASSLB在500个循环后显示71%的容量保留.

结论:

  • 兴奋剂改善了晶格结构,减少了离子迁移的能量障碍,并使可逆水化/脱水成为可能.
  • 开发的耐高湿度化物电解质是ASSLBs工业化的有希望的候选人.