在电极上的水凝电解质的现场聚合使灵活的全水凝超级电容器能够适应低温
Yijing Zhang1,2, Yue Sun1,2, Jingya Nan1
1Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Key Laboratory of Biomass Energy and Material, Jiangsu Province, Nanjing, Jiangsu, 210042, China.
Small (Weinheim an der Bergstrasse, Germany)
|February 5, 2024
概括
这项研究介绍了一种新型全凝超级电容器,其低温性能得到了提高. 它克服了结和粘附问题,在寒冷的环境中提供可靠的灵活电子产品.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 全凝超级电容器为可穿戴设备提供灵活性和安全性.
- 关键的挑战包括电极电解质粘附性差以及在低温下结.
研究的目的:
- 开发一个全凝超级电容器,具有强大的接口接触和防性能.
- 为了使灵活的电子产品在零度以下的温度下可靠运行.
主要方法:
- 在现场聚合水凝电解质到水凝电极上.
- 将化 (ZnCl2) 加入到水凝电解质中.
- 在广泛的温度范围内测试电化学性能和机械稳定性 (-60°C至20°C).
主要成果:
- 通过协同效应和拓纠实现了强大的界面粘附.
- 加入ZnCl2可以防止结,确保灵活性和耐疲劳性,低至-60°C.
- 证明了高能量密度 (11 mWh cm−2) 和90%的电容保留在-10,000个周期的-40°C.
- 超级电容器在-40°C下经历了2000次紧张周期,没有故障.
结论:
- 开发的全凝超级电容器表现出极好的低温电化学性能和机械稳定性.
- 这项工作为灵活的储能设备提供了可行的策略,可以适应寒冷的环境.
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